1.01201.0500 AMMONIUM PEROXODISULFATE MERCK

Description Catalogue Number 101201 Replaces AX1340; AX1340-1; AX1340-20; AX1340-3 Synonyms Ammonium persulfate, Peroxidisulfuric acid diammonium salt Product Information CAS number 7727-54-0 Grade ACS,Reag. Ph Eur Hill Formula H₈N₂O₈S₂ Chemical formula (NH₄)₂S₂O₈ Molar Mass 228.20 g/mol HS Code 2833 40 00 Quality Level MQ300 Physicochemical Information Density 1.980 g/cm3 Melting Point 120 °C (decomposition) pH value 3.2 (100 g/l, H₂O, 20 °C) Bulk density 900 kg/m3 Solubility 620 g/l Toxicological Information LD 50 oral LD50 Rat 742 mg/kg Safety Information according to GHS Hazard Pictogram(s) Hazard Pictogram(s) Hazard Pictogram(s) Hazard Pictogram(s) Hazard Statement(s) H272: May intensify fire; oxidizer. H302: Harmful if swallowed. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335: May cause respiratory irritation. Precautionary Statement(s) P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of water. P304 + P340 + P312: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Signal Word Danger RTECS SE0350000 Storage class 5.1B Oxidizing hazardous materials WGK WGK 1 slightly hazardous to water Disposal 22 Inorganic peroxides and oxidants as well as bromine and iodine should be rendered harmless by reduction with acidic sodium thiosulfate solution (Cat. No. 106513); container D or E. Slightly soluble oxidants should be collected separately in container E or I. Safety Information Categories of danger oxidizing, harmful, irritant, sensitizing Storage and Shipping Information Storage Store at +15°C to +25°C. Transport Information Declaration (railroad and road) ADR, RID UN 1444 , 5.1, III Declaration (transport by air) IATA-DGR UN 1444 , 5.1, III Declaration (transport by sea) IMDG-Code UN 1444 , 5.1, III, Segregation Group: 2 (Ammonium compounds) Specifications Assay (iodometric) ≥ 98.0 % Insoluble matter ≤ 0.005 % Titrable free acid ≤ 0.04 meq/g Chloride, Chlorate (as Cl) ≤ 0.001 % Heavy metals (as Pb) ≤ 0.001 % Fe (Iron) ≤ 0.001 % Mn (Manganese) ≤ 0.00005 % Residue on ignition (as SO₄) ≤ 0.05 %

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