1.01261.1000 ANILINE MERCK

Description Catalogue Number 101261 Synonyms Aminobenzene, Phenylamine, Benzenamine, Aminobenzene Overview EMSURE® grade solvents are suitable for a broad spectrum of classical lab applications, and are frequently used in regulated and highly demanding lab applications. EMSURE® provides worldwide best and most extensive product specifications. We declare our EMSURE® range to be in compliance with the ACS, with the reagent part of the European Pharmacopoeia (Reag. Ph Eur) and also with the ISO standards. Product Information CAS number 62-53-3 EC index number 612-008-00-7 EC number 200-539-3 Hill Formula C₆H₇N Chemical formula C₆H₅NH₂ Molar Mass 93.13 g/mol HS Code 2921 41 00 Structure formula Image Structure formula Image Quality Level MQ300 Physicochemical Information Boiling point 184 °C (1013 hPa) Density 1.021 g/cm3 (20 °C) Explosion limit 1.2 - 11 %(V) Flash point 70 °C Ignition temperature 540 °C Melting Point -6 °C pH value 8.8 (36 g/l, H₂O, 20 °C) Vapor pressure 0.49 hPa (20 °C) Solubility 36 g/l Toxicological Information LD 50 dermal LD50 Rabbit 840 mg/kg Safety Information according to GHS Hazard Pictogram(s) Hazard Pictogram(s) Hazard Pictogram(s) Hazard Pictogram(s) Hazard Pictogram(s) Hazard Statement(s) H301 + H311 + H331: Toxic if swallowed, in contact with skin or if inhaled. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H341: Suspected of causing genetic defects. H351: Suspected of causing cancer. H372: Causes damage to organs through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects. Precautionary Statement(s) P273: Avoid release to the environment. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor. P302 + P352 + P312: IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P311: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Signal Word Danger Storage class 6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials WGK WGK 3 highly hazardous to water Disposal 9 Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535). Safety Information Categories of danger toxic, carcinogenic, irritant, sensitizing, mutagenic, dangerous for the environment Storage and Shipping Information Storage Store at +2°C to +30°C. Transport Information Declaration (railroad and road) ADR, RID UN 1547 , 6.1, II Declaration (transport by air) IATA-DGR UN 1547 , 6.1, II Declaration (transport by sea) IMDG-Code UN 1547 , 6.1, II, Marine Pollutant: P Specifications Purity (GC) ≥ 99.5 % Identity (IR) conforms Nitrobenzene (GC) ≤ 0.003 % Sulfated ash ≤ 0.005 % Water ≤ 0.1 %

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