1.06727.1000 NICKEL ll SULFATE HEXAHYDRATE MERCK

Description Catalogue Number 106727 Description Nickel(II) sulfate hexahydrate Product Information CAS number 10101-97-0 EC index number 028-009-00-5 EC number 232-104-9 Grade ACS Hill Formula NiO₄S * 6 H₂O Chemical formula NiSO₄ * 6 H₂O Molar Mass 262.84 g/mol HS Code 2833 24 00 Quality Level MQ300 Physicochemical Information Density 2.07 g/cm3 pH value 4.3 - 4.7 (100 g/l, H₂O, 20 °C) Bulk density 1000 kg/m3 Solubility 650 g/l Toxicological Information LD 50 oral LD50 Rat 361 mg/kg Safety Information according to GHS Hazard Pictogram(s) Hazard Pictogram(s) Hazard Pictogram(s) Hazard Pictogram(s) Hazard Statement(s) H302 + H332: Harmful if swallowed or if inhaled. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled. H341: Suspected of causing genetic defects. H350i: May cause cancer by inhalation. H360D: May damage the unborn child. H372: Causes damage to organs through prolonged or repeated exposure if inhaled. H410: Very toxic to aquatic life with long lasting effects. Precautionary Statement(s) P202: Do not handle until all safety precautions have been read and understood. P273: Avoid release to the environment. P280: Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P312: IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of water. P308 + P313: IF exposed or concerned: Get medical advice/ attention. Signal Word Danger Storage class 6.1D Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects WGK WGK 3 highly hazardous to water Disposal 15 Heavy metal-containing solutions and solids: container E. Stir Raney nickel (also: Urushibara nickel) in the form of an aqueous suspension into hydrochloric acid (Cat. No. 100312) until dissolved (container E). Neither Raney nickel itself nor any filter residues should be allowed to dry out, otherwise they will spontaneously ignite in air. In this context, heavy metal means any compound of antimony, arsenic, cadmium, chromium(VI), copper, lead, nickel and tin, as well as these subtances in metallic form, if they are classified as hazardous (acc. to AbfallverzeichnisV - Waste Catalogue Ordinance, Appendix 3). Other heavy metals should be collected separately. Safety Information Categories of danger carcinogenic, toxic for reproduction, toxic, irritant, mutagenic, sensitizing, dangerous for the environment Storage and Shipping Information Storage Store at +2°C to +30°C. Transport Information Declaration (railroad and road) ADR, RID UN 3077 , 9, III Declaration (transport by air) IATA-DGR UN 3077 , 9, III Declaration (transport by sea) IMDG-Code UN 3077 , 9, III, Marine Pollutant: P Specifications Assay (complexometric) 99.0 - 101.0 % Identity passes test Insoluble matter ≤ 0.005 % Chloride (Cl) ≤ 0.001 % Total nitrogen (N) ≤ 0.001 % Ca (Calcium) ≤ 0.005 % Co (Cobalt) ≤ 0.002 % Cu (Copper) ≤ 0.002 % Fe (Iron) ≤ 0.001 % K (Potassium) ≤ 0.01 % Mg (Magnesium) ≤ 0.005 % Mn (Manganese) ≤ 0.002 % Na (Sodium) ≤ 0.03 % Pb (Lead) ≤ 0.001 % Zn (Zinc) ≤ 0.002 %

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